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ChemInform Abstract: Investigating Cation Binding in the Polyoxometalate-Super-Crown [P8W48O184]40-.

✍ Scribed by Thomas Boyd; Scott G. Mitchell; David Gabb; De-Liang Long; Leroy Cronin

Publisher: John Wiley and Sons
Year: 2012
Weight: 33 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201205022

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The complex host-guest chemistry… …of the crown-type cluster [P 8 W 48 O 184 ] 40À has been studied by a combination of 31 P NMR spectroscopy and isothermal titration calorimetry. This cluster which was originally reported in 1985 is witnessing a recent surge in interest. Herein its selectivity for