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Inversion of the sign of the magnetic isotope effect of mercury in photolysis of substituted dibenzylmercury

✍ Scribed by A. L. Buchachenko; V. L. Ivanov; V. A. Roznyatovskii; A. Kh. Vorob’ev; Yu. A. Ustynyuk

Book ID
110160575
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
146 KB
Volume
420
Category
Article
ISSN
0012-5016

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✍ E.N. Step; V.F. Tarasov; A.L. Buchachenko 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 339 KB

Silicon isotope selection induced by magnetic isotope effects has been discovered in the photolysis of a silyl-containing ketone, PhCH,COSi( CH,),Ph. Silicon and carbon atom isotope selection occurs most effkiently when the photolysis is directed via the triplet radical-pair mechanism. This conclusi