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Inversion of stereoselectivity in epoxidation of steroids by magnesium monoperoxyphthalate induced by manganese porphyrins

✍ Scribed by René Ramasseul; Corinne Scheer; Manuella Tavares; Jean-Claude Marchon

Publisher
Elsevier Science
Year
1990
Weight
277 KB
Volume
63
Category
Article
ISSN
0304-5102

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A series of Mn III porphyrins progressively halogenated in the electrophilic pathway of addition and a stereospecific pathway of oxygen insertion, the former being disfavoured β-pyrrolic positions was employed to catalyse the epoxidation of cis-stilbene by iodosylbenzene, and to study by electron-wi