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Inversion of spin levels in Ni2+: Zn(BF4)2· 6H2O under uniform compression and the effect of transition coincidence

✍ Scribed by I. M. Krygin; A. A. Prokhorov; G. N. Neilo; A. D. Prokhorov


Book ID
110128831
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
65 KB
Volume
43
Category
Article
ISSN
1063-7834

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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa