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Inverse vibrational distributions of photofragments

โœ Scribed by Vladimir Z. Kresin; William A. Lester Jr.


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
409 KB
Volume
87
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The rn3trt\ clr'merz dejcr!blag the transition from 3 bound to an unbound state m pho~od~oci~tion oia linear trlatomle molecule is found to y&d an mvcrsc vtbntton3l dist~bullon when the rccail energy of the pho~oila~ment bless than or ampanble to the mtern~l energy.


๐Ÿ“œ SIMILAR VOLUMES


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Vibrationally excited HCO radicals have been observed in the photodissociation of acetaldehyde in a supersonic jet with the pump-probe technique. The threshold wavelength for the bending and CO-stretching excitations was 308.7 and 302.6 nm, respectively. The nascent vibrational distribution relative

Speed distributions of the photofragment
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A method is developed for extracting the photofragment speed distribution function from a velocity aligned Doppler spectrum. This method is used to determine the distribution function of HCl produced by 193 nm photodissociation of vinyl chloride. The speed distribution of the Cl fragment is determin

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โœ D.J. Donaldson; Stephen R. Leone ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 602 KB

## With minor modifications to commercial instrumentation, time-resolved FTIR emission spectroscopy is demonstrated for the determination of photofragment internal state distributions. Vinyl chloride and dichloroethylene photolysis at 193 nm serve as test cases and exhibit high signal-to-noise.