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`Inverse-Electron-Demand' Diels-Alder Reactions of (E)-3-Diazenylbut-2-enes in Water

✍ Scribed by Orazio A. Attanasi; Lucia De Crescentini; Paolino Filippone; Francesco Fringuelli; Fabio Mantellini; Mizio Matteucci; Oriana Piermatti; Ferdinando Pizzo

Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
137 KB
Volume
84
Category
Article
ISSN
0018-019X

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Inverse Electron Demand Diels-Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine. -Tetrazine (I) is used as an azadiene equivalent for inverse electron demand Diels -Alder reactions with alkynes and alkenes to give functionalized dichloropyridazines, e.g. (III), (V), and (VII). -(SPAREY, T.