ChemInform Abstract: Inverse Electron Demand Diels—Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine.
✍ Scribed by T. J. SPAREY; T. HARRISON
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Inverse Electron Demand Diels-Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine.
-Tetrazine (I) is used as an azadiene equivalent for inverse electron demand Diels -Alder reactions with alkynes and alkenes to give functionalized dichloropyridazines, e.g. (III), (V), and (VII). -(SPAREY, T.
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Preparation of Novel Tricyclic Diazo Carbapenems: Application of Inverse Electron Demand Diels-Alder Reactions of 3,6-Bis(methylthio)- 1,2,4,-The construction of the novel tricyclic carbapenem precursor (VIII) (a single, unspecified diastereomer) is accomplished via the inverse electron demand Diels