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ChemInform Abstract: Inverse Electron Demand Diels—Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine.

✍ Scribed by T. J. SPAREY; T. HARRISON


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Inverse Electron Demand Diels-Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine.

-Tetrazine (I) is used as an azadiene equivalent for inverse electron demand Diels -Alder reactions with alkynes and alkenes to give functionalized dichloropyridazines, e.g. (III), (V), and (VII). -(SPAREY, T.


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Preparation of Novel Tricyclic Diazo Carbapenems: Application of Inverse Electron Demand Diels-Alder Reactions of 3,6-Bis(methylthio)- 1,2,4,-The construction of the novel tricyclic carbapenem precursor (VIII) (a single, unspecified diastereomer) is accomplished via the inverse electron demand Diels