Intramolecular vibrational redistribution and vibrational predissociation in 9-cyanoanthracene-Ar van der waals complexes
β Scribed by I. M. Gulis; A. I. Komyak; K. A. Saechnikov; D. S. Umreiko; V. A. Tsvirko
- Book ID
- 110621446
- Publisher
- Springer US
- Year
- 1998
- Tongue
- English
- Weight
- 915 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0021-9037
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π SIMILAR VOLUMES
We propose a local modes description of stretching motion and enera transfer in photocxcited IzS,, ran der Wa;lls compleses. In a simple local modes model. we find decrcasin, 0 efficiency of vibrationA predissociation as the size of the complex grows. in qualitative agreement with recent esperimcnts
We presented a calculation of the total and partial decay widths of vibrational Ε½ . predissociation VP of the HeI molecule for low initial vibrational excitations from the 2 Ε½ . lowest van der Waals vdW state with total angular momentum J s 0. A time-dependent golden rule wave-packet method was empl