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Vibrational predissociation dynamics and internal rotation in aromatic van der Waals complexes

✍ Scribed by B. D. Gilbert; C. S. Parmenter; M. -C. Su; H. -K. Oh; Z. -Q. Zhao


Publisher
Springer
Year
1994
Tongue
English
Weight
681 KB
Volume
59
Category
Article
ISSN
0721-7269

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πŸ“œ SIMILAR VOLUMES


Local modes analysis of vibrational pred
✍ Michael E. Kellmann πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 464 KB

We propose a local modes description of stretching motion and enera transfer in photocxcited IzS,, ran der Wa;lls compleses. In a simple local modes model. we find decrcasin, 0 efficiency of vibrationA predissociation as the size of the complex grows. in qualitative agreement with recent esperimcnts

Total and partial decay widths in vibrat
✍ Daren Guan; Xian Zhao; Conghao Deng; John Z. H. Zhang πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 180 KB πŸ‘ 2 views

We presented a calculation of the total and partial decay widths of vibrational Ε½ . predissociation VP of the HeI molecule for low initial vibrational excitations from the 2 Ε½ . lowest van der Waals vdW state with total angular momentum J s 0. A time-dependent golden rule wave-packet method was empl

The Rotational Spectra, Structure, Inter
✍ C.W Gillies; J.Z Gillies; S.J Amadon; R.D Suenram; F.J Lovas; H Warner; R Malloy πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 206 KB

Pulsed-beam Fourier transform microwave spectroscopy was used to observe and assign the rotational spectra of the argonketene van der Waals complex. Tunneling of the hydrogen or deuterium atoms splits the a-and b-type rotational transitions of H 2 CCO-Ar, H 2 13 CCO-Ar, H 2 C 13 CO-Ar, and D 2 CCO-A

Rotational Spectrum, Dynamics, and Bond
✍ Biagio Velino; Aldo Millemaggi; Walther Caminati πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 104 KB

From the free jet millimeter-wave spectra of four isotopomers of the weakly bonded oxiraneβ€’ β€’ β€’Kr complex, information on the equilibrium conformation, dynamics, and dissociation energy has been deduced. A C s symmetry is found for the complex, with Kr lying in the Οƒ v plane of symmetry of oxirane.

Vibrational predissociation of highly vi
✍ M. Aguado; P. Villarreal; G. Delgado-Barrio; P. Mareca; J.A. Beswick πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 451 KB

In this paper a three-dimensional quantum model to study vibrational predissociation of van der Waals molecules is applied to the +-He complex for very high vibrational (SO 4 ~14 64) of the 12 subunit The vibrations are described in the distorted-wave diabatic approximation while rotations are treat