ti general formula of the probability of vibrational transitions in diatomic molecules is formulated with specific consideration of vibration-vibration energy transfer for nonresonant cases. An application to HZ-H2 collisions shows an excellent agreement of the present formulation with exact quantum
Intramolecular vibration-vibration energy transfer in triatomic molecules
β Scribed by H.K. Shin
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 418 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
A classical model for V-R and V-V energy transfer between two dissimilar diatomic molecules is proposed. For the exponential repulsive potentid, in the limit as the rotation of the mplecules goes to zero, the presenr model reduces to the previous resu!ts for V-T and V-V energy transfer. For the hydr
The vibration-vibration ene=y transfer of HCI gas initially excited to the tirst vibrational level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process is found to be 0.9 x IO5 secwl tom-'.
## Previous works have reported vibration-vibration and vibration-translation transfer rates in CHJF and CHg F-X mixtures. fn this letter we report the study of the fast V-V transfer rate populating the 3~3, u1 and ~4 states of CHJF. GaseousCHsF was initially exited to the ~3 state by a TEA CO2 la