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Intramolecular rearrangement of N-alkyl-2-thio-2-(2′-chloroalkoxy)-1,3,2-azaoxaphosphorinanes

✍ Scribed by O. N. Nuretdinova


Book ID
112437497
Publisher
Springer
Year
1976
Tongue
English
Weight
276 KB
Volume
25
Category
Article
ISSN
1573-9171

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Allylic phenyl and methyl sulfides bearing a strategically positioned electrophilic center have been shown to undergo concomitant C2,31-sigmatropic rearrangement and intramolecular N-alkylation upon oxidative conversion to allylic sulfilimines and treatment with aqueous base. This one-pot transforma