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Intramolecular Reactions of Cyclopropylcarbinyl, Cyclobutyl, and Allylcarbinyl Cationic Systems

✍ Scribed by Bayless, J.; Friedman, L.; Smith, J. A.; Cook, F. B.; Shechter, H.

Book ID
126465767
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
357 KB
Volume
87
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Small-ring compoundsβ€”XXXVIII: Calculatio
Small-ring compoundsβ€”XXXVIII: Calculations of the relative stabilities of intermediates in the interconversion reactions of cyclopropylcarbinyl, cyclobutyl, and allylcarbinyl derivatives by the LCAO method
✍ M.E.H. Howden; John D. Roberts πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 695 KB

The simple LCAO method with corrections for angle strain indicates that bicyclobutonium cations are likely to be more stable than homoallylic cations. The reverse is predicted to be true for the corresponding free-radical and anionic derivatives. The results are in accord with experiment. THE very