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Additions and Corrections-The Nature of the Intermediate in Carbonium Ion-type Interconversion Reactions of Cyclobutyl, Cyclopropylcarbinyl and Allylcarbinyl Derivatives

✍ Scribed by Roberts, John; Mazur, Robert


Book ID
127141289
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
142 KB
Volume
73
Category
Article
ISSN
0002-7863

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Small-ring compoundsβ€”XXXVIII: Calculatio
✍ M.E.H. Howden; John D. Roberts πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 695 KB

The simple LCAO method with corrections for angle strain indicates that bicyclobutonium cations are likely to be more stable than homoallylic cations. The reverse is predicted to be true for the corresponding free-radical and anionic derivatives. The results are in accord with experiment. THE very