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Intramolecular penning ionization in benzonitrile—rare gas clusters

✍ Scribed by W. Kamke; B. Kamke; H.U. Kiefl; I.V. Hertel

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
394 KB
Volume
122
Category
Article
ISSN
0009-2614

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✦ Synopsis

A supersonic beam of benzonirrile (Bn) seeded into He. Ar or Kr was ionized by VUV phorons rrom the electron s~oragc ring BESSY ar Berlin. Phomioniution efficiency curves were measured Tar Bn. Bn2, Bn -Ar and Eln Kr. Resonance peaks in the PIE curves show that excilalion energy or the rare gas alom is transferred LO the Bn molecule wilhin the hclerogeneous clusler. leading LO ionization of the molecule and fragmenlation of the cluster.

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