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Intramolecular Pauson–Khand reaction of optically active aza-Baylis–Hillman adducts

✍ Scribed by Shingo Ishikawa; Fumiaki Noguchi; Hidemitsu Uno; Akio Kamimura

Book ID: 104097540
Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 190 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.02.115

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✦ Synopsis

The intramolecular Pauson-Khand reaction of aza-Baylis-Hillman adducts, which were prepared through the thio-Michael/imino-aldol domino reaction of optically active sulfinimines, was examined and gave optically active cis-and trans-pyrrolidine-fused cyclopentenones in a stereoselective manner.

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