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ChemInform Abstract: Intramolecular Pauson—Khand Reaction of Optically Active Aza-Baylis—Hillman Adducts.

✍ Scribed by Shingo Ishikawa; Fumiaki Noguchi; Hidemitsu Uno; Akio Kamimura

Book ID
102047316
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction of alkyl‐substituted adducts (I) provides predominantly pyrrolidine‐fused cyclopentanones with cis‐configuration.

📜 SIMILAR VOLUMES

Intramolecular Pauson–Khand reaction of
Intramolecular Pauson–Khand reaction of optically active aza-Baylis–Hillman adducts
✍ Shingo Ishikawa; Fumiaki Noguchi; Hidemitsu Uno; Akio Kamimura 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 190 KB

The intramolecular Pauson-Khand reaction of aza-Baylis-Hillman adducts, which were prepared through the thio-Michael/imino-aldol domino reaction of optically active sulfinimines, was examined and gave optically active cis-and trans-pyrrolidine-fused cyclopentenones in a stereoselective manner.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v