𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intramolecular participation of the amide group in the hydrolysis of p-nitrophenyl N-(bromoacetyl) anthranilate

✍ Scribed by Jean-Jacques Béchet; Robert Alazard; Alain Dupaix; Colette Roucous

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
653 KB
Volume
3
Category
Article
ISSN
0045-2068

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Metal Ion Catalysis in the Hydrolysis of
Metal Ion Catalysis in the Hydrolysis of Esters of 2-Hydroxy-1,10-phenanthroline: The Effects of Metal Ions on Intramolecular Carboxyl Group Participation
✍ Thomas H. Fife; M.P. Pujari 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 207 KB

Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes

Possible neighbouring group participatio
Possible neighbouring group participation of a nitro-group in the conversion of 3-hydroxymethyl-2-(2-nitrophenyl)-1,2,3,4-tetrahydroisoquinoline into its 3-chloromethyl derivative
✍ Michael J. Donaghy; Stephen P. Stanforth 📂 Article 📅 2005 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 79 KB

The alcohol 12 reacted with 4-toluenesulfonyl chloride in boiling dichloromethane solution to give the chlorinated product 13 rather than the expected tosylate 3 by a mechanism that could involve neighbouring group participation of the nitro-substituent. In contrast, the isomeric alcohol 15 reacted