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Intramolecular Orbital Alignment Observed in the Photodissociation of [D1]Thiophenol

✍ Scribed by Jeong Sik Lim; Ivan S. Lim; Kyoung-Seok Lee; Doo-Sik Ahn; Yoon Sup Lee; Sang Kyu Kim

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
519 KB
Volume
118
Category
Article
ISSN
0044-8249

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Inside Cover: Control of Intramolecular
Inside Cover: Control of Intramolecular Orbital Alignment in the Photodissociation of Thiophenol: Conformational Manipulation by Chemical Substitution (Angew. Chem. Int. Ed. 10/2008)
✍ Jeong Sik Lim; Yoon Sup Lee; Sang Kyu Kim 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB

Conformational control by chemical substitution influences the content of the wavepacket propagating along the SÀH coordinate of thiophenol. The wide spread of the wavepacket at the conical intersection, induced by the conformation of the SÀH torsional angle, diminishes the probability of diabatic p