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Control of Intramolecular Orbital Alignment in the Photodissociation of Thiophenol: Conformational Manipulation by Chemical Substitution

✍ Scribed by Jeong Sik Lim; Yoon Sup Lee; Sang Kyu Kim

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
513 KB
Volume
47
Category
Article
ISSN
0044-8249

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Inside Cover: Control of Intramolecular
Inside Cover: Control of Intramolecular Orbital Alignment in the Photodissociation of Thiophenol: Conformational Manipulation by Chemical Substitution (Angew. Chem. Int. Ed. 10/2008)
✍ Jeong Sik Lim; Yoon Sup Lee; Sang Kyu Kim 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB

Conformational control by chemical substitution influences the content of the wavepacket propagating along the SÀH coordinate of thiophenol. The wide spread of the wavepacket at the conical intersection, induced by the conformation of the SÀH torsional angle, diminishes the probability of diabatic p