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Intramolecular nucleophilic addition of an organorhodium(i) to a nitrile

✍ Scribed by Miura, Tomoya; Nakazawa, Hiroki; Murakami, Masahiro

Book ID
126552611
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
277 KB
Volume
22
Category
Article
ISSN
1359-7345

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## Deprotonation of 2-phenyl-1-tosylaziridine 1 with butyl lithium gives an anion that cyclizes to 4 by an intramolecular nucleophilic aromatic addition. Treatment of derivatives 5, 6 with a Grignard reagent produces aziridines 10, 11.