Intramolecular Michael Additions: Copper(I) Chloride-Mediated Conjugate Addition of Vinyltrimethylstannane Functions to .alpha.,.beta.-Unsaturated Ketones
β Scribed by Piers, Edward; McEachern, Ernest J.; Burns, Patricia A.
- Book ID
- 127215093
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 264 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
AbstractΓA new copper(I)-mediated method for effecting intramolecular conjugate addition of alkenyl functions to a,b-unsaturated ketone systems is reported. Treatment of the substrates 14, 15, 19Β±21, 22 and 23 with 2.5 equiv. of CuCl in DMF at room temperature affords excellent yields of the corresp
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