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Intramolecular kinetic isotope effects in alkane hydroxylations catalyzed by manganese and iron porphyrin complexes

✍ Scribed by Sorokin, Alexander; Robert, Anne; Meunier, Bernard


Book ID
115509126
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
926 KB
Volume
115
Category
Article
ISSN
0002-7863

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Three iron(III)-metal-free porphyrin dimers linked covalently with a flexible butoxy chain at the paru position of the two phenyl rings have been prepared and characterized. The hydroxylation of cyclohexane catalyzed by these dimers with molecular oxygen under mild condition has been studied prelimi