Intramolecular Hydrocarbonation of α-Alkynyl Malononitriles Catalyzed by Palladium Olefin Complexes
✍ Scribed by Dr. Naofumi Tsukada; Prof. Dr. Yoshinori Yamamoto
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 535 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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Pd(PPh3)4-catalyzed cyclizations of N-allyl(croty1, or 3-butenyl),N-butenyloxy derivatives and of an allyl(2-butenyloxy) ether give pyrrolidines, piperidines and a tetrahydrofuran in good yields. Hexahydroindoles and octahydroquinolines are thus obtained from the corresponding N-(2-or 3-butenyl),N-(