Cross-Coupling of Aryl Iodides with Malononitrile Catalyzed by Palladium N- Heterocyclic Carbene Complex System
β Scribed by Cheng-Wei Gao; Xiao-Chun Tao; Tao-Ping Liu; Ji-Ling Huang; Yan-Long Qian
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 226 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0256-7660
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## Abstract The combination of rhodium(I) and Nβhetercyclic carbenes (NHC) was found to be effective as a catalyst for crossβcoupling reactions of aryl arenesulfonates with arylboronic acids, which gave rise to the desired biaryl compounds in good yields.
on the occasion of his 65th birthday The Suzuki cross-coupling reaction, which involves the coupling of aryl boronic acid with an organohalide, has proven to be a versatile tool in organic synthesis. [1] Recent developments have led to catalysts based on sterically demanding, basic phosphanes allow