Intramolecular Hydroamination of Dithioketene Acetals: An Easy Route To Cyclic Amino Acid Derivatives
✍ Scribed by Xu, Hai-Chao; Moeller, Kevin D.
- Book ID
- 127324816
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 380 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1523-7060
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Chiral tertiary amines have been examined as enantioselective decarboxylation-reprotonation reagents for the synthesis of a-amino acids via a-aminomalonates. N-Acetyl pipecolic acid ethyl ester, as a model compound, was obtained in good yield and 52% enantiomeric excess using a quinidine derived bas
The synthesis of a series of novel (t-amino acids based on the nucleophilic substitution of protected 2-amino-4-bromobutanoic acid (1) is described. Basic, acidic or neutral amino acids can be obtained; chimerical amino acids carrying a coenzyme type structure in the side chain, multifunctional amin