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Intramolecular ?ene? reactions of thioaldehydes

✍ Scribed by Choi, Samuel S-M.; Kirby, Gordon W.


Book ID
120823210
Publisher
The Royal Society of Chemistry
Year
1988
Tongue
English
Weight
211 KB
Volume
3
Category
Article
ISSN
0022-4936

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The I .74iencs 3ac with a double-activated cnophile moiety undzrgo thermal and zinc bromide catalyzed intramolecular ene rcactions lcading to rrurts-1.2-disubstitutcd cyclohexanes 4a-c in up to 8 9 9 ~ yield, highly diastcrcoselectively. The synthesis of cyclulicxaim from 1.7-diencs has not been fca