Intramolecular Electron Transfer in Fullerene/Ferrocene Based Donor-Bridge-Acceptor Dyads. -Fluorescence and time-resolved flash photolytic investigations of a series of compounds such as (I)-(III). -
Intramolecular Electron Transfer in Fullerene/Ferrocene Based Donor−Bridge−Acceptor Dyads
✍ Scribed by Guldi, Dirk M.; Maggini, Michele; Scorrano, Gianfranco; Prato, Maurizio
- Book ID
- 117998474
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 337 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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Intramolecular electron transfer rates for ion formation in bridged donor/acceptor systems have been determined using fluorescence lifetime measurements. The data show a weak dependence of the rate on the donor/acceptor distance as well as a dependence on the electronic structure of the spacer. Thes
## Abstract Photoinduced electron‐transfer processes in fullerene‐based donor–acceptor dyads (DBA) in homogeneous and cluster systems are summarized. Stabilization of charge has been achieved through the use of fullerene substituted‐aniline/heteroaromatic dyads with tunable ionization potentials