Intramolecular Electron Transfer in Donor−Spacer−Acceptor Systems with Alkylamide Spacers
✍ Scribed by Lewis, Frederick D.; Wagner-Brennan, Jill M.; Denari, John M.
- Book ID
- 126922174
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 140 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Intramolecular electron transfer rates for ion formation in bridged donor/acceptor systems have been determined using fluorescence lifetime measurements. The data show a weak dependence of the rate on the donor/acceptor distance as well as a dependence on the electronic structure of the spacer. Thes
Photoinduced electron transfer rates are reported for a pair of rigid bichromophoric molecules, l(8) and 3( 8), in a variety of solvents. It was found that intramolecular electron transfer in l( ) is up to five times faster than in 3( 8). X-ray crystallography revealed that the cyclopentyl ring atta