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Intramolecular Electron Transfer between Noncovalently Linked Donor and Acceptor in a [2]Catenane

✍ Scribed by Hu, Yi-Zhen; van Loyen, Dietmar; Schwarz, Oliver; Bossmann, Stefan; Dürr, Heinz; Huch, Volker; Veith, Michael


Book ID
126938924
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
64 KB
Volume
120
Category
Article
ISSN
0002-7863

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Photoinduced electron transfer rates are reported for a pair of rigid bichromophoric molecules, l(8) and 3( 8), in a variety of solvents. It was found that intramolecular electron transfer in l( ) is up to five times faster than in 3( 8). X-ray crystallography revealed that the cyclopentyl ring atta