Photoinduced electron transfer (ET) is studied in a series of novel molecules containing a dimethoxynaphthalene (DMN) donor and either a pyridine (P) or N-methylpyridinium (P-Me + ) acceptor covalently linked via a rigid norbornalogous bridge (n sigma bonds in length). ET rates of the order of l0 ~°
✦ LIBER ✦
Intra- and intermolecular electron transfer reactions in covalently linked donor-acceptor molecules
✍ Scribed by A.M. Brun; S.M. Hubig; M.A.J. Rodgers; W.H. Wade
- Book ID
- 113281634
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 495 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0168-583X
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## Abstract Poly(γ‐benzyl‐L‐glutamate) having a terminal dimethylaminoanilide group as an electron donor (D) and a terminal 3,5‐dinitrobenzoyl group as an electron acceptor (A) (A‐[Glu(OBzl)]~__n__~‐D) was synthesized by the __N__‐carboxyanhydride method. Polymer samples were fractionated by gel ch