Intramolecular Diels—Alder Reactions of Siloxacyclopentene Constrained Trienes.
✍ Scribed by Geoff T. Halvorsen; William R. Roush
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 41 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Excellent diasterofacial selection has been observed in asymmetric Diels-Alder cycloadditions of E,E-triene-imides 3 and 6.
The first examples of intramolecular Diels-Alder reactions on indoles indicate that this reaction may be employed for the direct preparation of highly functionalized dihydroindoles. The hybridization of the atoms in the tether plays a crucial role.