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Intramolecular Diels—Alder reaction of 4-(N-furfuryl)aminobut-1-enes. New approach to the synthesis of 6,8a-epoxyoctahydroisoquinoline (3-aza-11-oxatricyclo[6.2.1.01,6]undec-9-ene) derivatives

✍ Scribed by F. I. Zubkov; E. V. Nikitina; K. F. Turchin; A. A. Safronova; R. S. Borisov; A. V. Varlamov

Book ID
111607698
Publisher
Springer
Year
2004
Tongue
English
Weight
432 KB
Volume
53
Category
Article
ISSN
1573-9171

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✍ J Zylber; A Tubul; P Brun 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 184 KB

The title compound can be obtained with up to five asymmetric centres of known absolute configuration by a diastereoselective intramolecular Diels-Alder reaction between optically active N-substituted fuffurylamines and maleic anhydride, in which the chirality is transferred from one stereocentre to