✦ LIBER ✦

Asymmetric synthesis of methyl N-(1-phenylethyl)-3-aza-10-oxatricyclo[5.2.1.01,5]-4-oxo dec-8-en-6-carboxylate by an intramolecular Diels-Alder reaction

✍ Scribed by J Zylber; A Tubul; P Brun

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 184 KB
Volume: 6
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(95)00018-k

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound can be obtained with up to five asymmetric centres of known absolute configuration by a diastereoselective intramolecular Diels-Alder reaction between optically active N-substituted fuffurylamines and maleic anhydride, in which the chirality is transferred from one stereocentre to the four others.

📜 SIMILAR VOLUMES

Synthesis of a Novel Series of 10-Oxa-3-

Synthesis of a Novel Series of 10-Oxa-3-aza-tricyclo[5.2.1.01,5]dec-8-en-4-ones Through an Intramolecular Diels—Alder Reaction.

✍ Karen L. Milkiewicz; Irina B. Neagu; Daniel J. Parks; Tianbao Lu 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 100 KB 👁 1 views

Synthesis of a novel series of 10-oxa-3-

Synthesis of a novel series of 10-oxa-3-aza-tricyclo[5.2.1.01,5]dec-8-en-4-ones through an intramolecular Diels–Alder reaction

✍ Karen L. Milkiewicz; Irina B. Neagu; Daniel J. Parks; Tianbao Lu 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 126 KB

The synthesis of a novel series of 10-oxa-3-aza-tricyclo[5.2.1.0 1,5 ]dec-8-en-4-ones through the use of the intramolecular Diels-Alder reaction is presented. The use of this reaction allows for the synthesis of functionalized polycyclic systems in a stereocontrolled manner.

Study of Regioselectivity of Intramolecu

Study of Regioselectivity of Intramolecular Cyclization of N-(m-R-Phenyl)- and N-(α-Naphthyl)-2-allyl (methallyl)-6-carboxy-4-oxo-3-aza-10-oxatricyclo [5.2.1.01,5]dec-8-enes.

✍ F. I. Zubkov; E. V. Boltukhina; E. V. Nikitina; A. V. Varlamov 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Intramolecular Diels—Alder Reaction of 4

Intramolecular Diels—Alder Reaction of 4-(N-Furfuryl)aminobut-1-enes. New Approach to the Synthesis of 6,8a-Epoxyoctahydroisoquinoline (3-Aza-11-oxatricyclo[6.2.1.01,6]undec-9-ene) Derivatives.

✍ F. I. Zubkov; E. V. Nikitina; K. F. Turchin; A. A. Safronova; R. S. Borisov; A. 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 185 KB 👁 2 views

ChemInform Abstract: Five-Membered 2,3-D

ChemInform Abstract: Five-Membered 2,3-Dioxo Heterocycles. Part 66. Reaction of 3-Aroyl-1H-pyrrolo[2,1-][1,4]benzoxazine-1,2,4-triones with α-Enamino Esters. Crystalline and Molecular Structure of Methyl 11-Benzoyl-2-o-hydroxyphenyl-3,4,10-trioxo-6,9-diphenyl-7-oxo-2,9-diazat ricyclo[6.2.1.01,5]undec-5-ene-8-carboxylate.

✍ N. L. Racheva; Z. G. Aliev; A. N. Maslivets 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v