Depending on the reaction conditions the intramolecular Diels-Alder reaction of furan-diene 14 yields predominantly either one of two adducts 16a and 16b , which possess the necessary --functionality for eventual transformation into corticosteroids. The dienophile was intro-
Intramolecular diels-alder reaction with furan-diene. An expeditious entry into a functionalized gibbane.
โ Scribed by Werner M Grootaert; Pierre J De Clercg
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 227 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
A short synthesis of a functionalized gibbane molecular Diels-Alder reaction of furan-diene mers, tentatively identified as 14a and 14b.
-zoic acid in 7 steps.
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