The 6-step sequence to trienone 2, a known intermediate for the total synthesis of periplanone-B, involves the conversion of 2 into 5 using dilithiated propadiene, the IMDA of 4 to E-adducts 1 and 6, the conversion of 2 to diol S via a radical anion promoted cleavage of the oxygen bridge, and a in-s
Thermodynamically controlled asymmetric induction: Applications with the intramolecular Diels-Alder reaction involving a furan diene
✍ Scribed by Simon Woo; Brian A. Keay
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 288 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0957-4166
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