On reacting Meldrum's acid with butyraldehyde in MeCN in the presence of catalytical amounts of piperidine, we obtained a 52 % yield of the dimer ii (m.p. 1 17-1 18"), probably the same compound that was believed to be the Michaeladduct iii [13]. Reduction of dimer ii with NaBH, [5c] gave the corres
β¦ LIBER β¦
Intramolecular decomposition of isopropylidene diazomalonate (diazo Meldrum's acid)
β Scribed by Kammula, Seetha L.; Tracer, Howard L.; Shevlin, Philip B.; Jones, Maitland
- Book ID
- 127337902
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 277 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-3263
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