Acid-catalyzed decomposition of an α-keto diazo endoperoxide

✍ Scribed by Hong-Son Ryang; Christopher S. Foote

• Book ID: 104220892
• Publisher: Elsevier Science
• Year: 1982
• Tongue: French
• Weight: 155 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)87393-1

✦ Synopsis

Two different decomposition modes of a-keto diazo endoperoxide 1 are described.

One is the Brgnsted acid-catalyzed elimination of the diazo group leading to rearranged per-