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Intramolecular cycloadditions of arylketenes with alkenes: Reactions of 5-arylbicyclo[3.2.0]heptan-6-ones

✍ Scribed by Barry B. Snider; Maho Niwa


Book ID
107858407
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
309 KB
Volume
29
Category
Article
ISSN
0040-4039

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## Abstract Dehydrochlorination of chlorinated 5‐hydroxy‐2‐oxabicyclo[3.2.0]heptan‐4‐ones, 3a‐c, which were obtained from the photo[2+2]cycloadditions between 4‐hydroxy‐3(2__H__)‐furanone 1 and chloroethylenes, with triethylamine gave 2‐ethenyl‐3(2__H__)‐furanones 4a,b or 2‐(2‐cyanoethyl)‐3(2__H__)