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Intramolecular [2 + 2] Photocycloaddition of Alkenes Incorporated in a Carbohydrate Template. Synthesis of Enantiopure Bicyclo[3.2.0]heptanes and -[6.3.0]undecanes

✍ Scribed by Banerjee, Shyamapada; Ghosh, Subrata


Book ID
121869397
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
204 KB
Volume
68
Category
Article
ISSN
0022-3263

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Synthesis of Ξ”3a,5a-Bicyclo[3.2.0]hepten
✍ Prof. Dr. W. Kirmse; Dipl.-Chem. K. H. Pook πŸ“‚ Article πŸ“… 1966 πŸ› John Wiley and Sons 🌐 English βš– 123 KB πŸ‘ 1 views

diameter afforded two fractions with specific optical rotations [a]:& = +4.3 and -2.5 O . After a second passage the rotations were [a]:& = +7.5 ' and -5 '' (1 % in CHCI3).