Intramolecular condensation of steroidal Ilfi-acetoxy-17a-carbaldehydes offers a synthetic route to 19-nor-17,17-spirofactones. A cycloaddition-mediated route to ring D modified 19-not-steroids has recently been described, 2 in which 17~-acetoxy-3-methoxyestra-1,3,5(10)-triene-14,l7a-dicarbaldehyde(
✦ LIBER ✦
Intramolecular condensation of steroidal 17α-formyl 17β-acetates: model studies on 19-norsteroids, and a route to 3-methoxy-19- nor-17α-pregna-1,3,5(10).Triene 21,17-carbolactone
✍ Scribed by James R Bull; Lynne M Steer
- Book ID
- 108371862
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 872 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0040-4020
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