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Intramolecular charge recombination in carotenoid—porphyrin—pyromellitimide triads

✍ Scribed by Atsuhiro Osuka; Hiroko Yamada; Satoshi Shinoda; Koichi Nozaki; Takeshi Ohno

Book ID
103032689
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
386 KB
Volume
238
Category
Article
ISSN
0009-2614

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✦ Synopsis

The temperature dependence of the charge-recombination rate in photochemically generated ion-pair states (carotenoid, C)+-(porphyrin, P)-(pyromellitimide, Im)-has been shown to vary with a spacer between C and P. The triad with a 1,4-phenylene spacer exhibits only weak temperature dependence, while triads with methylene-bis_(l,4-phenylene) and benzanilide spacers exhibit distinct biphasic temperature dependence.

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