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Intramolecular C−H Activation Involving a Rhodium−Imidazol-2-ylidene Complex and Its Reaction with H 2 and CO

✍ Scribed by Huang, Jinkun; Stevens, Edwin D.; Nolan, Steven P.

Book ID
120244496
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
65 KB
Volume
19
Category
Article
ISSN
0276-7333

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C–H Activation with Iridium(III) and Rho
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✍ Xiao-Yi Yi; Ka-Wang Chan; Enrique Kwang Huang; Yiu-Keung Sau; Ian D. Williams; W 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 427 KB

## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat