𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intramolecular Catalysis of Amide Isomerization: Kinetic Consequences of the 5-NH- -N a Hydrogen Bond in Prolyl Peptides

✍ Scribed by Cox, Christopher; Lectka, Thomas


Book ID
120211599
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
281 KB
Volume
120
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


GIAO, DFT, AIM and NBO analysis of the N
✍ Andrei V. Afonin; Igor A. Ushakov; Alexander V. Vashchenko; Evgeniy V. Kondrasho 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB

## Abstract In the series of diaminoenones, large high‐frequency shifts of the ^1^H NMR of the NH group in the __cis__‐position relative to the carbonyl group suggests strong NH···O intramolecular hydrogen bonding comprising a six‐membered chelate ring. The NH···O hydrogen bond causes an increas