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Intramolecular carbon-hydrogen insertions of alkylidenecarbenes. 2. Stereochemistry and isotope effects

โœ Scribed by Gilbert, John C.; Giamalva, David H.; Baze, Mark E.

Book ID
126205936
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
1008 KB
Volume
50
Category
Article
ISSN
0022-3263

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The thermal unimolecular decomposition of diethyl carbonate-1,1,1,2,2-d5 has been examined in the high-pressure-limiting region. The observed chemistry is consistent with a simple, competitive two-channel model: The intramolecular isotope effect k H / k D has been determined, and the relative Arrhe