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Insertion of an alkylidenecarbene into the silicon-hydrogen bond. Isotope effect for the reaction

โœ Scribed by Gilbert, John C.; Giamalva, David H.


Book ID
127158417
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
298 KB
Volume
50
Category
Article
ISSN
0022-3263

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Reaction path for the insertion reaction
โœ William R. Rocha; Wagner B. De Almeida ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 210 KB ๐Ÿ‘ 2 views

The reaction pathway for the insertion reaction of SnCl into the Pt-Cl 2 ลฝ . ลฝ . bond on the cis-Pt Cl PH compound was investigated at the ab initio MO level of 2 3 2 theory. The optimized structure obtained for the transition state indicates that this reaction proceeds through a three-center transi