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Intramolecular Activation of a Disila[2]molybdenocenophanedihydride: Synthesis and Structure of a [1],[1]Metalloarenophane

✍ Scribed by Holger Braunschweig; Manuela Gross; Krzysztof Radacki; Christian Rothgaengel


Book ID
101566786
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
315 KB
Volume
47
Category
Article
ISSN
0044-8249

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Synthesis and Structure of 1,2-Diphenyl-
✍ Lars Wesemann; Yves Ramjoie; Michael Trinkaus; Beate Ganter πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 121 KB πŸ‘ 1 views

Diphenyl-o-silaborane (1) can be obtained by sublimation as colourless crystalline material in a yield of 23%. The disilaborane 1 was characterized by NMR spectroscopy, mass spectrometry and X-ray structure analysis. The neutral closo cluster 1 reacts with [Zr(NMe 2 ) 4 ] or [Ta(NMe 2 ) 5 ] to give