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Intramolecular [2+2] Photocycloaddition Reactions as an Entry to the 2-Oxatricyclo[4.2.1.04, 9]nonan-3-one Skeleton of Lactiflorin

✍ Scribed by Dr. Ping Lu; Dr. Eberhardt Herdtweck; Prof. Dr. Thorsten Bach


Book ID
112006648
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
761 KB
Volume
7
Category
Article
ISSN
1861-4728

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Molecular oxygen trapping reaction of alkenes with 2,3-pyrrolidinedione derivatives was developed using a Mn(lll)-induced oxidation system. AIkenes and 2,3-pyrrolidinediones were treated with manganese(Ill) acetate in acetic acid under a stream of dry air, giving l-hydroxy-8-aza-2,3-dioxabicyclo[4.3