Reactions of substituted 8-oxatricyclo[3.2.1.02,4]octan-6-ones and 9-oxatricyclo[3.3.1.02,4]nonan-6-ones with methylmagnesium bromide and lithium aluminum hydride
β Scribed by A. P. Molchanov; V. V. Diev; Chan Quang Tung; R. R. Kostikov
- Book ID
- 111465102
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 133 KB
- Volume
- 45
- Category
- Article
- ISSN
- 1070-4280
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reduction of 3-oxatricyclo[3.2.1.0 2,4 ]octane-endo-6-carbonitrile by lithium aluminum hydride is completed by the formation of exo-2-hydroxy-4-azatricyclo[4.2.1.0 3,7 ]nonane with the structure confirmed (1) by the analysis of 1 H, 13 C, 14 N, and 17 clo[4.2.1.0 3,7 ]nonane prepared by an alter
## Abstract Alkylation of 4,4,6βtrimethylβ2βcyclohexenone (**1**) in toluene in the presence of sodium bis(trimethylsilyl)amide proceeds smoothly to give high yields of compounds **2**. Irradiation (Ξ»= 366 nm) of the 6βallylβ4,4,6βtrimethylβ2βcyclohexenones **2aβc** yields mixtures of the isomeric