✦ LIBER ✦

Interpretation of the Brønsted dependence in a quantum-mechanical model of proton transfer from CH acids to bases

✍ Scribed by D. É. Khoshtariya

Book ID: 112441241
Publisher: Springer
Year: 1990
Tongue: English
Weight: 652 KB
Volume: 26
Category: Article
ISSN: 0040-5760
DOI: 10.1007/bf00943874

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The Energy Profile of Proton Transfer fr

The Energy Profile of Proton Transfer from Brønsted Acids to Terminal Hydrides in Transition Metal Complexes Can Be Estimated by Combining in situ IR and NMR Spectroscopy

✍ Natalia V. Belkova; Ekaterina V. Bakhmutova; Elena S. Shubina; Claudio Bianchini 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

The enthalpy and entropy changes relative to the stepwise reaction of [(triphos)Re(CO) 2 H] with perfluoro-tert-butyl alcohol in CH 2 Cl 2 to give first the hydrogen-bonded adduct [(triphos)Re(CO) 2 H•••HOC(CF 3 ) 3 ] and then the stable non-[a] A. N.

The kinetics of proton transfer from oct

The kinetics of proton transfer from octaphenylsubstituted tetraazaporphyrin to organic bases in benzene

✍ O. A. Petrov; E. L. Kuz’mina; O. G. Helevina; V. E. Maizlish 📂 Article 📅 2011 🏛 International Academic Publishing Co (Nauka/Interp 🌐 English ⚖ 196 KB

A quantum chemical study of the formatio

A quantum chemical study of the formation of cyanide (CN−) and acetate () ions in astrophysical ices via proton transfer from HCN, HNC, or CH3COOH to NH3

✍ David E. Woon 📂 Article 📅 2012 🏛 Elsevier 🌐 English ⚖ 738 KB

Rates of Proton Transfer from Carboxylic

Rates of Proton Transfer from Carboxylic Acids to Dianions, CO 2 (CH 2 ) p CO 22- , and Their Significance to Observed Negative Charge States of Proteins in the Gas Phase †

✍ Blades, Arthur; Peschke, Michael; Verkerk, Udo; Kebarle, Paul 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 84 KB

C(.alpha.)-Proton Transfer from 2-(1-Hyd

C(.alpha.)-Proton Transfer from 2-(1-Hydroxybenzyl)oxythiamin: The Unit Bronsted Slope Overestimates the Amount of Bond Formation to the Base Catalyst in the Transition State

✍ Washabaugh, Michael W.; Stivers, James T.; Hickey, Karen A. 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 425 KB

NON-AQUEOUS TITRATIONS AS A TOOL IN THE

NON-AQUEOUS TITRATIONS AS A TOOL IN THE STUDY OF MOLECULAR RECOGNITION PHENOMENA. USES IN DISTINGUISHING HYDROGEN BONDING FROM PROTON TRANSFER, THE MEASUREMENT OF COMPLEX INDUCED pKa SHIFTS, AND THE ABILITY TO DISTINGUISH THE CATALYTIC ROLES OF GENERAL ACIDS AND BASES

✍ Christine L. Hannon; Dwayne A. Bell; Anne M. Kelly-Rowley; Larry A. Cabell; Eric 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 3 views

Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho