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Internal rotation and structure of thiophenol and 4-fluorothiophenol studied by microwave spectroscopy and quantum chemistry

✍ Scribed by Niels Wessel Larsen; Leif Schulz


Book ID
108213006
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
343 KB
Volume
920
Category
Article
ISSN
0022-2860

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Internal Rotation, Quadrupole Coupling,
✍ I Merke; W Stahl; S Kassi; D Petitprez; G Wlodarczak πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 334 KB

The microwave spectrum of (CH 3 ) 3 SiCl and its isotopic species (CH 3 ) 3 Si 37 Cl, (CH 3 ) 3 29 SiCl, (CH 3 ) 3 30 SiCl, and ( 13 CH 3 )(CH 3 ) 2 SiCl has been studied in the frequency range of 3 to 40 GHz. The barrier to internal rotation, the chlorine quadrupole coupling, and the structure were